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Self-supported transition metal phosphide based electrodes as high-efficient water splitting cathodes

Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 494-508 doi: 10.1007/s11705-018-1732-9

Abstract: Combining novel self-supporting structure and high-performance transition metal phosphides (TMP) showsIn this review, we try to provide a comprehensive analysis of the design and fabrication of various self-supportedThe material structures together with catalytic performances of self-supported electrodes are presentedThe simple and one-step methods to fabricate self-supported TMP electrodes are also highlighted.Finally, the challenges and perspectives for self-supported TMP electrodes in water splitting application

Keywords: transition metal phosphide     self-supported electrode     electrocatalysis     hydrogen evolution reaction    

Oxygen-deficient MoO/NiS heterostructure grown on nickel foam as efficient and durable self-supported

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 4,   Pages 437-448 doi: 10.1007/s11705-022-2228-1

Abstract: High-performance and ultra-durable electrocatalysts are vital for hydrogen evolution reaction (HER) during water splitting. Herein, by one-pot solvothermal method, MoOx/Ni3S2 spheres comprising Ni3S2 nanoparticles inside and oxygen-deficient amorphous MoOx outside in situ grow on Ni foam (NF), to assembly the heterostructure composites of MoOx/Ni3S2/NF. By adjusting volume ratio of the solvents of ethanol to water, the optimized MoOx/Ni3S2/NF-11 exhibits the best HER performance, requiring an extremely low overpotential of 76 mV to achieve the current density of 10 mA∙cm‒2 (η10 = 76 mV) and an ultra-small Tafel slope of 46 mV∙dec‒1 in 0.5 mol∙L‒1 H2SO4. More importantly, the catalyst shows prominent high catalytic stability for HER (> 100 h). The acid-resistant MoOx wraps the inside Ni3S2/NF to ensure the high stability of the catalyst under acidic conditions. Density functional theory calculations confirm that the existing oxygen vacancy and MoOx/Ni3S2 heterostructure are both beneficial to the reduced Gibbs free energy of hydrogen adsorption (|∆GH*|) over Mo sites, which act as main active sites. The heterostructure effectively decreases the formation energy of O vacancy, leading to surface reconstruction of the catalyst, further improving HER performance. The MoOx/Ni3S2/NF is promising to serve as a highly effective and durable electrocatalyst toward HER.

Keywords: molybdenum oxides     oxygen vacancies     heterostructure     electrocatalysts     hydrogen evolution reaction    

Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater

Frontiers of Chemical Science and Engineering 2021, Volume 15, Issue 6,   Pages 1427-1443 doi: 10.1007/s11705-021-2108-0

Abstract: The selection and preparation of electrode materials and electrocatalysts play an important role on theThe aim of this paper is to introduce the most excellent high-efficiency electrode materials and electrocatalystsMany electrode materials such as metal electrode materials, boron-doped diamond anode materials and three-dimensionalelectrode are introduced in detail.The composite treatment of active electrode and electrocatalyst are extensively examined.

Keywords: electrocatalytic oxidation     electrode     electrocatalysis     dye wastewater    

Quality control based on electrode displacement and force in resistance spot welding

Chuntao JI, Lipeng DENG

Frontiers of Mechanical Engineering 2010, Volume 5, Issue 4,   Pages 412-417 doi: 10.1007/s11465-010-0114-x

Abstract: The behaviors of electrode displacement and force during spot welding under various conditions, suchas different weld currents, electrode forces, and welding times, were studied.An electrode force peak is observed and believed relevant to the sufficient nugget size.

Keywords: aluminum     electrode displacement     electrode force     nugget size     data acquisition    

A novel flow electrode capacitive deionization device with spindle-shaped desalting chamber

Frontiers of Environmental Science & Engineering 2023, Volume 18, Issue 4, doi: 10.1007/s11783-024-1800-y

Abstract:

● A spindle-shaped influent chamber was designed and equipped in FCDI system.

Keywords: Spindle-shaped chamber     Desalination performance     Flow electrode capacitive deionization    

A comprehensive assessment on the durability of gas diffusion electrode materials in PEM fuel cell stack

Arunkumar JAYAKUMAR

Frontiers in Energy 2019, Volume 13, Issue 2,   Pages 325-338 doi: 10.1007/s11708-019-0618-y

Abstract: The crucial and expensive component involved in it is the gas diffusion electrode (GDE) and its degradation

Keywords: PEM fuel cell     gas diffusion electrode(GDE)     gas diffusion layer(GDL)     membrane electrode assembly     durability    

Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 8,   Pages 1065-1074 doi: 10.1007/s11705-023-2313-0

Abstract: In this present study, the resultant lignin-derived porous carbon was used as the electrode of a supercapacitor

Keywords: lignin     porous carbon     electrode     supercapacitor    

Characterization of electrode fouling during electrochemical oxidation of phenolic pollutant

Xuefeng Liu, Shijie You, Fang Ma, Hao Zhou

Frontiers of Environmental Science & Engineering 2021, Volume 15, Issue 4, doi: 10.1007/s11783-020-1345-7

Abstract: Abstract • Electrode fouling is characterized by non-destructive characterization. • Electrode foulingElectrode fouling is a problem that commonly occurs during electro-oxidation water purification.This study focused on identifying the fouling behavior of Pt electrode associated with the formationThe in situ electrochemical measurements and non-destructive observation of the electrode morphologyelectrode that was controlled by anode potential.

Keywords: Electro-oxidation     Electrode fouling     Polymeric film     Chloride ions    

3D Network nanostructured NiCoP nanosheets supported on N-doped carbon coated Ni foam as a highly active

Miaomiao Tong, Lei Wang, Peng Yu, Xu Liu, Honggang Fu

Frontiers of Chemical Science and Engineering 2018, Volume 12, Issue 3,   Pages 417-424 doi: 10.1007/s11705-018-1711-1

Abstract: Herein, a self-supported electrode composed of 3D network nanostructured NiCoP nanosheets grown on N-dopedAs a bifunctional electrocatalyst, the NiCoP/NF@NC electrode needs overpotentials of 31.8 mV for hydrogen

Keywords: bimetallic phosphides     N-doped carbon     self-support     hydrogen evolution     oxygen evolution    

Electroreduction of hexavalent chromium using a porous titanium flow-through electrode and intelligent

Frontiers of Environmental Science & Engineering 2023, Volume 17, Issue 8, doi: 10.1007/s11783-023-1697-x

Abstract:

● Titanium-based flow-through electrode achieved high Cr(VI) reduction

Keywords: Flow-through electrode     Hexavalent chromium     Heavy metals     Neural network     Artificial intelligence    

Latest development of double perovskite electrode materials for solid oxide fuel cells: a review

Shammya AFROZE, AfizulHakem KARIM, Quentin CHEOK, Sten ERIKSSON, Abul K. AZAD

Frontiers in Energy 2019, Volume 13, Issue 4,   Pages 770-797 doi: 10.1007/s11708-019-0651-x

Abstract: Recently, the development and fabrication of electrode component of the solid oxide fuel cell (SOFC)have gained a significant importance, especially after the advent of electrode supported SOFCs.The function of the electrode involves the facilitation of fuel gas diffusion, oxidation of the fuel,The present review focuses on the various aspects pertaining to a potential electrode material, the doubleVarious methods adopted to determine the quality of electrode component have been provided in detail.

Keywords: double perovskites     electrode materials     hydrocarbon fuel     solid oxide fuel cells    

An antibiotic composite electrode for improving the sensitivity of electrochemically active biofilm biosensor

Frontiers of Environmental Science & Engineering 2022, Volume 16, Issue 8, doi: 10.1007/s11783-022-1518-7

Abstract:

• Antibiotic azithromycin employed in graphite electrode for EAB biosensor

Keywords: AZM@GP composite electrode     EAB-biosensor     Water quality early-warning    

Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

Frontiers of Chemical Science and Engineering 2023, Volume 17, Issue 10,   Pages 1440-1449 doi: 10.1007/s11705-023-2333-9

Abstract: The composite electrode of CoNiSx and Ti3C2TxTx, which helped increase the specific surface area and pore volume of the electrodethat the in-situ doping of the cobalt element promoted the electrochemical performance of the electrode

Keywords: MXene     supercapacitor     cobalt doping     structure characterization     electrochemical performance    

Quality monitoring of resistance spot welding based on electrode displacement characteristics analysis

ZHANG Pengxian, ZHANG Hongjie, CHEN Jianhong, MA Yuezhou

Frontiers of Mechanical Engineering 2007, Volume 2, Issue 3,   Pages 330-335 doi: 10.1007/s11465-007-0058-y

Abstract: First, twelve parameters related to weld quality are mined from electrode displacement signal on the

Preparation of a Pb loaded gas diffusion electrode and its application to CO

Ang LI, Hua WANG, Jinyu HAN, Li LIU

Frontiers of Chemical Science and Engineering 2012, Volume 6, Issue 4,   Pages 381-388 doi: 10.1007/s11705-012-1216-2

Abstract: A Pb loaded gas diffusion electrode was fabricated and used for the electroreduction of CO to formicThe preparation conditions of the gas diffusion electrode were optimized by adjusting the amounts ofThe electrochemical performance of the as-prepared gas diffusion electrode was studied by chronoamperometryThe optimized gas diffusion electrode showed good catalytic performance for the electroreduction of COefficiency of formic acid after 1 h of operation reached a maximum of 22% at -2.0 V versus saturated calomel electrode

Keywords: electroreduction     carbon dioxide     lead catalyst     gas diffusion electrode     formic acid    

Title Author Date Type Operation

Self-supported transition metal phosphide based electrodes as high-efficient water splitting cathodes

Yan Zhang, Jian Xiao, Qiying Lv, Shuai Wang

Journal Article

Oxygen-deficient MoO/NiS heterostructure grown on nickel foam as efficient and durable self-supported

Journal Article

Application of electrode materials and catalysts in electrocatalytic treatment of dye wastewater

Journal Article

Quality control based on electrode displacement and force in resistance spot welding

Chuntao JI, Lipeng DENG

Journal Article

A novel flow electrode capacitive deionization device with spindle-shaped desalting chamber

Journal Article

A comprehensive assessment on the durability of gas diffusion electrode materials in PEM fuel cell stack

Arunkumar JAYAKUMAR

Journal Article

Fabricating sustainable lignin-derived porous carbon as electrode for high-performance supercapacitors

Journal Article

Characterization of electrode fouling during electrochemical oxidation of phenolic pollutant

Xuefeng Liu, Shijie You, Fang Ma, Hao Zhou

Journal Article

3D Network nanostructured NiCoP nanosheets supported on N-doped carbon coated Ni foam as a highly active

Miaomiao Tong, Lei Wang, Peng Yu, Xu Liu, Honggang Fu

Journal Article

Electroreduction of hexavalent chromium using a porous titanium flow-through electrode and intelligent

Journal Article

Latest development of double perovskite electrode materials for solid oxide fuel cells: a review

Shammya AFROZE, AfizulHakem KARIM, Quentin CHEOK, Sten ERIKSSON, Abul K. AZAD

Journal Article

An antibiotic composite electrode for improving the sensitivity of electrochemically active biofilm biosensor

Journal Article

Enhanced electrochemical performance of CoNiS@TiCT electrode material through doping of cobalt element

Journal Article

Quality monitoring of resistance spot welding based on electrode displacement characteristics analysis

ZHANG Pengxian, ZHANG Hongjie, CHEN Jianhong, MA Yuezhou

Journal Article

Preparation of a Pb loaded gas diffusion electrode and its application to CO

Ang LI, Hua WANG, Jinyu HAN, Li LIU

Journal Article